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ABSTRACT
A monitoring program to determine the seasonal distribution of sulfur and nitrogen from the atmosphere and a greenhouse experiment to evaluate the absorption of atmospheric SO2 by alfalfa (Medicago sativa) was conducted. Atmospheric SO2 levels at all rural and urban locations were low in the summer months and increased markedly in the winter months and, on the average, the values in urban areas were about twice those in rural areas. The SO2 collected 2 km from an industrial location was 10 to 15 times as high as the urban locations. At a distance of 5 km this value dropped to levels comparable to urban areas and to rural levels at 10 km. Sulfur (as SO4) in precipitation followed the same seasonal and location trends as did SO2 with 16, 42, and 168 kg of S/ha per yr being deposited in rural, urban and industrial locations, respectively. An overall state average of 30 kg S/ha per yr was estimated. Sulfur-deficient alfalfa plants grown in a greenhouse at Madison from January to May obtained as much as 73% of their S from the atmosphere. The amount of NH4-N and organic N deposited by precipitation was highest during the spring months and lowest during the winter months. Both NH4-N and organic-N were higher in areas adjacent to barnyards than in areas removed from the barnyard. However, NO3-N deposition was relatively constant for all locations and was slightly lower in the winter months. Total N additions ranged from 13 to 30 kg/ha per yr, and an overall state average of about 20 kg/ha per yr was estimated.
Key Words: sulfur dioxide alfalfa air pollution precipitation S precipitation N
1 Contribution from the Department of Soils, University of Wisconsin, Madison, Wis. 53706. Research supported by the College of Agriculture and Life Sciences. University of Wisconsin, Madison, Farmers Union Central Exchange, The Sulphur Institute, and Tennessee Valley Authority. Presented before Div. S-4, Soil Science Society of America, Aug. 26, 1970, Tucson, Ariz.
2 Postdoctoral Fellow, Associate Professor, and Professor of Soils, respectively.
3 Appreciation is expressed to Mrs. K. L. Chen for the nitrogen analysis and to all of the cooperators throughout the state who assisted in collecting the samples.
Received for publication July 29, 1971.
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